(i2)«fHa*ft«lzat-5l\T»M**ifcBIBB«
(i9) vt&atumifmvM
(43) SRtaMB
2003 *f 3 n 13 B (13.03.2003)
PCT
llllll II (III I II I II Ml II II III II MP
(io) mm^mm^
WO 03/021706 Al
(51) UlSftPrfrfl 7 : H01M 10/40, C23C 14/04, H01B 1/06
(21) sstttM-t:
(22) SfgfcfjMB:
(25) BISUiHa>«B:
(26) BBttBBatfi:
(30) ffiftttf'-*:
f#BS2001-265510
PCT/JP02/08897
2002 ^9/^2 0 (02.09.2002)
B*f§
2001 ^9^3 B (03.09.2001) JP
(71) fflHA( r *S*»<*Ta)*SSSf=Ot\-CJ:«T«
S§&gfci££*± (MATSUSHITA ELECTRIC INDUS-
TRIAL CO., LTD.) [JP/JP]; t 571-8501 *BSJ& P^Srfi
^HII 0 0 6#ife Osaka (JP).
(72)
(75)
*Wt/lillAf*ll:oL>tfl)^: fiP*
(HIGUCHI,Hiroshi) [JP/JP]; =f 610-0353 SfPJfr St
HiSrlT 1-9-1 7 Kyoto (JP). &M &
=. (ITO,Shuji) [JP/JP]; f 631-0001 SSI
TfT dttll^fi 5-1 1-2 Nara (JP). ft ft
(IWAMOTO,Kazuya) [JP/JP]; =r 593-8304 *B£j& »rB
^j^#0T 2 T 1 9|20§ Osaka (JP). & iESF
(UGAJI,Masaya) [JP/JP]; T 572-0802 SSJU
rtT fT±9 1 9-1 A 1 1 07 Osaka (JP). f&B
(MATSUDA,Hiromu) [JP/JP]; ¥666-0261 HEft HIS
ffl»*JI|BrttJS£2-1-1 1 L 2 0 9 Hyogo (JP).
IS IS (MINO,Shinji) [JP/JP]; =f 567-0036 *E
fff £*r?T ±ffi»1 TS 2-1 4-4 0 2 Osaka (JP).
*B*# (SHIBANO,Yasuyuki) [JP/JP]; T 599-8273
*BEJ& aS^/^^ffll 1 0 7 3-1 4 Osaka (JP).
mm H- (INABA,Junichi) [JP/JP]; t 560-0003 *
HEJ& mg^BT 1 TS 2 6-1 3 Osaka (JP).
*TJ§ (HONDA,Kazuyoshi) [JP/JP]; f 569-0056
*8Si& iS$r|T $m0T 1-5-3 4 Osaka (JP). 00*
41 £ (OKAZAKI,Sadayuki) [JP/JP]; f 576-0054 *
BSJfr SB* SB 4-9-5 0 8 Osaka (JP). «# C
(SAKAI,Hitoshi) [JP/JP]; f 572-0055 *EJff ftgjll
m^0^0T3-1 4-5 1 2 Osaka (JP). ffijf J:«T
(TAKAI,Yoriko) [JP/JP]; T 560-0002 *{£J& * 8
£3T@ 2 2§8§ Osaka (JP).
(74) ftSA: ¥#*Qfi&, tt(ISHn,Kazuoetal.);T541-0041
*G£Jft XErfi * AEftiR 2TI 3§6§ ftj&OJ*
tf;U Osaka (JP).
(81) H£B (HPfy: AE, AG, AL, AM, AT, AU, AZ, BA, BB,
BG, BR, BY, BZ, CA, CH, CN, CO, CR, CU, CZ, DE, DK,
DM, DZ, EC, EE, ES, FI, GB, GD, GE, GH, GM, HR, HU,
ID, 1L, IN, IS, JP, KE, KG, KP, KR, KZ, LC, LK, LR, LS,
LT, LU, LV, MA, MD, MG, MK, MN, MW, MX, MZ, NO,
NZ, OM, PH, PL, PT, RO, RU, SD, SE, SG, SI, SK, SL, TJ,
TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, YU, ZA,
ZM, ZW.
(84) }g£H ($M)i ARIPO (GH, GM, KE, LS, MW,
MZ, SD, SL, SZ, TZ, UG, ZM, ZW), i-7v7^
(AM, AZ, BY, KG, KZ, MD, RU, TJ, TM), 3 - O y
= (54) Title: METHOD FOR MANUFACTURING ELECTROCHEMICAL DEVICE
H (54) sh<d«»: n%it¥m*<D$i£_?5&
o
O
(57) Abstract: A method for manufacturing an electrochemical device so
containing stacked first collector, first electrode active substance layer, solid
electrolytic layer, second electrode active substance layer, and second col-
lector to provide an electrochemical device having a layer structure free
from damage of material characteristics comprises the step of supplying
atoms, ions, or clusters constituting the first and second electrode active
substance layers or solid electrolytic layer to the substrate under irradiation
with electrons or electromagnetic waves having an energy predetermined
according to the composition of the first and second electrode active sub-
stance layers, or solid electrolytic layer to form the first and second elec-
trode active substance layers, and solid electrolytic layer.
WO 03/021706 Al I Ufl IiniUI II If If!l Hill lif I i D lif llfll IIIII Kill (111! Hfll IUI IIIIM (III Bll fill
#W (AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, 2 - K& fteroBSiil-OlNT It, JtJSSgfi $
GB, GR, IE, IT, LU, MC, NL, PT, SE, SK, TR), OAPI ft &PaHM y KD#E&C:tf «S tlTl^Z T=l- KiKS
Sf (BF.BJ.CF.CG.CI.CM.GA.GN.GQ.GW.ML.MR, OT# -f ^VXy* - h J £#18.
NE, SN, TD, TG).
(57)
WO 03/021706 PCT/JP02/08897
t
m m m
«$nTV>£ (^a^fgS 3 3 8 6 2 5 #) • fcfrXh, MB^U
±z\z&oxm<zntcmmmm*%*rz±®fcnm\z. &m&mm*
*««*»icfejfl£*is*ftf fctxtt, licoOb, LiMn 2 o 4 ,
LiNi0 2 , V2O5, Mo0^i;^T i S 2 ^ t'©^f B K^»^f^5
@i$fiiicttis B H B i0fe(D t^agotot^fts. tens
WO 03/021706
2
PCT/JP02/08897
tl/TIt 0iJ;ifc£L i 2 . 9 P Oa. 3 N 0 . ae&cfctf 7^7 7 XL i »P0 4
- L i aS i OifcWtgtfSn, mB«10 " 6 ~ 1 0 - 4 S c m-'CD-f
08*«L i «S - S i S », Li 2 S-P 2 S6> L I.S-BjSi,
AK*BI*a:^*aslaUT#6n5Hfl:*»»*i:^Wr6n, ^ ft e>
i # in b# k: jp $ n , mwmmnm<Dum^m^(Dum^m^Tm^^
± wr r £ > *o*«± ic« w- & n fc0#ii!?si©ag * ± if r ess
^S^#l¥8 - 2 8 7 9 0 1 #^afclB^$ft'rV5S. -rftfr-fe, U
»M©il»flittlSl±*J;^a6«t©«*ttra±©&»K:, Sf©#ffi^Jx
WO 03/021706
3
PCT/JP02/08897
|-*tft51©J:II, MiffiiSi5 2, aWIi5 3, ft.
HftStiHfcKJI 5 4*3<ktffg-&«#5 5 £, p< * X £ & if V>
g«ife»a 5 2 , m&mmnm 5 3 *3i^^-m®^tiaa 5 4
0 3 CTK-ntifi^S £CfgM£i±fcjfig£ia4&J;tflI! 5 {I^T. 0
t^§LiCoO!> LiNi0 2 , L iMnjO^itfL I VsOs&t*
»«0^<C!)eFalk;«It 3 0 0 ~ 3 5 0 < C#i5^ S 5 » £ ,
s^iti.utfe^-s. i3~5 %>m,m*w ntz>
WO 03/021706 PCT/JP02/08897
4
ft* cnSOSISfflK 09*tf8rH§¥8 - 2 8 7 9 0 1
L-fctf^T 1 0 0 e V£i±0fcx*;i^-0-Y;f>£J|B
HOWIES, H#«***©«flLk#lc«fcS^fr>fiSfl^0ffiT
n ± x \z & £ -f ^ >£-a*g{gT «atf«T * fc v> .
-ftmx.<bnz>tmm\z, mzm^vrcnm^mnu^zh^ ^
WO 03/021706
5
PCT/JP02/08897
■enT-, $fgBJ©atf)«, _kfc&©«i:3fc«Jfi«ji:/a-fe;*±©raH£
*1-5*&fc¥&^fc«J:tf*©S^#8fti£#1-5d£fc <&3.
m ib m - n & e ti k a * fc « m ib h # € m » i © *& j& c c x =f © jg ©
6 n fc x ^> ;p =p - £ # T 5 m ^ £ fc \$Q tit i& ft M M b & a* 6 Iff IB S ft ±
fc«|&"r*iltfc«J:?K HEi-tSffiftSfi, ffifBfi§-ilMM)i
^7^ttMi3@^m^®sft^^-rss!imi@ft*ii-rsji tft^^t-r
WO 03/021706
6
PCT/JP02/08897
saias«©iaft*«, MiBMMx5gn*^T^^$ns«^n©
jaft^amzfeK-rs. -r&t>ts, *mm\z, m-nm^
m 1 tt, *38W©^J6«!-?fflVifcffl|^^gfl|©«EII|0T?»*.
m 2 tt, *S5^©^Jfi«f||T?fflVifc3iJ©|«^^S«©«tllSHT»*.
WO 03/021706
7
PCT/JP02/08897
K B & fi & IB 1" S * © 0 T $ 3 ..
»ttfc£tf«B(fcBfcK9J'*"*fc»©HT!a*-.
B9H, SfcJWOT^^ ©
?g«*«fc^l9!fifl:B*KWrsfc»o0T?**.
H'lOtt, #58ip|©^M^l;:$*& 1 ©*?6©#tt£jKTB"ea&5.
Blllt ^IflCDSIMlMKff 1 ©*»©»ttS*tBTJ**.
B12tt, *5IWOSlllt«"lc«*)l 1 ©«»o«ftt*«f HT?**.
@14tt, L i C o OzOlp^ftitTJl'&St" i^feSo
€ £J6-T § fc ft © ft A; © M
ot,
WO 03/021706
8
PCT/JP02/08897
7,mm%, ^tc\^m^v<\t^m^iry^ts^\it^7,mmn.\zr
<5©##SLV».
Milt,
M#3S^©gm#&©ii#ico^TiBHj3-r<5.
( i ) m 1 ©» Strife
WO 03/021706
9
PCT/JP02/08897
tlSJl^^^T^IIT, <:*>£fcte#7X*~£, Mien-ma?^
Ha*fcttiri3^-*«^4&HJioiia^t«ko : f feasts wr«
©SSmtfi&tf, MIBS#«»»©«Jlfl:»ftJ;0*Vi©*«ff*
Wtfr*X^^*-©!lflEE (eV) P&iS (1) :
E.^E^ (7 0±«) X (pidi) 1/2
<5£*. -7^a^7, E.«m®ffitiSS©^tt'fbX^;i/^- (eV) ,
Pitt*Iffi«iaiOifi( (g/cm 3 ) , dittM«toJtfl©fe?«ft
(A) ) ftUfcfCDtfffULV*.
WO 03/021706
10
PCT/JP02/08897
©iHte*/i>{i© e ~ 2 = 0 . 1 tUZ> 2 -Z)<Dmx*lX%Zn%o ^ZX, if
5gBJfc£^T«4 > >i>tt£ 7 0 t 7 t U7c (-7^as£7) „
izmfiTz,
zee, □ n)v u a (Licoo 2 ) ©^©^utt;
T©<fc a n^m^ns. Bi4fcL icoojotsfttrjust. 1a
H(t l i c o 02*^#WfclinSftLfe«^©Hffli£«fc:«ks??Ey!is
t^JtiC (=5 8. 8 J/mo 1/K) O3/UMijf0AS1f
UfrZ 4 0 OtSirftitSif CItSi^;K-E (e V)
E = ATC/eN A =0. 41 (eV)
^£K:£/&Lfetl5?£#l;U;£L i 2 0 (s)£J;tfC o O (s) t IT,
L hO(s) + CoO (s)^L i (gas) + C o (gas) +20 (gas)
t ^ ? mftMKlfo\zmt Z> 9 e VPilOI^JK-SIlit
m \z , m 1 2 s m © tt k # hu i a s m # » jg © m n < t u m z m x u ^ & ?
WO 03/021706 PCT/JP02/08897
11
(ii) f&2©S!jfi;m
« s s <d urn \z J; d =? «e> £ * £ &m <d m m £ it w t s n t & #it t -r s .
5t«E (e V) Hffi£ (2) :
E.^E^ ( 7 0 ± a) X (p 2 T 2 ) 1/2
(ev) , p 2\zm=.nMm®nm<D±\z&z>m m#*mnm&it\tm
mfcm) (g/cm 3 ) , t z\$m-n®m%)nm<D±\z$>z>m
WO 03/021706
12
PCT/JP02/08897
fc »Si St b < «s 3S-f * > % is tr ft# x * Bis; \z T § o jW *
(in) ^3©S5g^fe
fflt:rgfc,fcO#jfcU
JB»t«l*M-oM*E (eV) Hffi£ (3) :
WO 03/021706 PCT/JP02/08897
E „^E^ ( 7 0 ± a) X ( p 3 d 3 ) 1/2
(5£>K -?ka^7, E.I4S#*»»lfl)jSttil:i*;K- (eV) ,
p 3«B- a 3@mtiMS©^m (g/cm 3 ) , d 3 \$m=.nM%mnmo
te^EK (A) ) Siifef ©jW£bV>.
*«ig«M©lK&£jB*.fcV* J; 5 ic.
W IB £ £ 6 © W m t 1 7 - § M S t 5 © 'ifi ft k b V i .
b< tt**^f *>*^«jT«tt5tf ^*H«icr b
^*fctt««»LT»s©3i«w'K:5(irs&T»*. ±abfcft*aiRic*w-*
BS*bT*<^B3fi«*a.
«fc^H#«#»Jifc«ffl "5"*
© & H it <k 0 ffi fc WSft fc S&ft rJIIT * 3 .
WO 03/021706
14
PCT/JP02/08897
a****) t, mm^mzm^t txit mz.\t. limo 2
(MttCo, N i , Mn, Fe, V) , LiMn 2 0 4 , L'i,-.Co.N,
VzOs, L i sN&^lXL i (L i 1/1T 1 1/1) 0 4&i:^#tf
Sfl3U >S>Jf!>A, L iaS-S i Sa-L I sPO«, fei^L isO-
V2OS- s i ot«ffc£#*tf ens.
*Jl/*-fc, ±BE:£ (1) ~ (3) %m&2l£2> ZttfifrSV^o MM
x*;i^-s±B5$ (1) ~ (3) te&£1-*J9rj£®««Tfcfsc£
#ig#3fca©x*;U3s- <igfe<bx*;i/*-) Tab f , Mlev-
l^ot, ±fE5£ (1) ~ (3) X*;]^-E*JSWfS
uotsit »a*®BM*R*#jfc-r*»'frfcferc*fc#& left*
its. $i;U£\ ±ism 3 (Dmmism® «t 5 l i ^©s&xm
#ffiV>««i£«RH®±fc, LTOL i 3PO4
-LhSi 0 4<D3»ll»*7^^-rS Z\th, *3&93fc«5±|B« 3 ©13
WO 03/021706
15
PCT/JP02/08897
SI ft 1 * fc » 3 { b « A * » J* f -5 « £ fc 5S £ 1" * gfc X * & tt £ » © *
WO 03/021706
16
PCT/JP02/08897
8, tt&mmm?m2 i, ^7x^-*i^xfifS2 2, #
ffl7 , 7X'7ig3 2, ^SSffl/7X"?ilffl^XiAf 3 3, 2**7**
-^iW^XMif^^XiAf 3 4, #£«UB77XTJKffl#X
i*A*3 5 > 7X:3?-&ckW#Xffim^Mffl#X^A« ; 3 6 , *f
'X^;P^-SSitS« 2 1 , 2 2, 3 1 , 3 2 , 4 1 *±^42*6, 2
OX*;m£-JHW*fr SMS0J$Pg§ 1 3
^7XTl 3 1 « «J:tf 3 2 tiAt^^X tbttt, 01 A ft! * A r ,
He, Neft«ktfXea^itf6n5. CftS O^StttfXtt,
W§gfTj&50^fc(iN 2 fti*©^X&iAf 3 5 :fe«ktf 3 6 ^
ft«4 1 fc«ktf 4 2 t 12-62 nraOillt
WO 03/021706
17
PCT/JP02/08897
4 0nm) , &£.tfU--tf-M&-?7X~?ytmti£<D, ^Xftii^^
#P§¥ 8 - 2 8 7 9 0 1 ^^^IS^OfiTK* 7 >7te> S7K
tt# 6*^*^5 5. ^W: feUt) £>1\ 10 0 nm£(T©g$fi
Tte, WAffLi CoO», LiMn 2 0 4 s LiNiOj, V 2 0 5 ,
M0O2, T i Si, L iV 2 Os, Lh-.Co.N, L i s -.Ni,N,
L i 3-0 C u a N > $5<ktfL i a-.M n .N & \i £> ft S »
tl«5*ffiS«H®©*-&«, L i #ftJR©«l» t?tt«H*ftffi**rb, ft
tt^JXil/Tlt W^lBHe, Ar, Ne, X e 43 <ktfN«fc£#3£tf 6
ft 3 .
WO 03/021706
18
PCT/JP02/08897
SBf*. Hffl^tfX^AP 7 ^5 7J^>j!f7S l~100scc mtiD .
5 x l 0 1 x l 0 "To r r g£®ffiafc«#T*
HHM 1
52, Li 2 S-SiS 2 -Li 3P0 4 TM$n^
S^m^Ml 5 3*«fctf L i C oOi"Tr*J*3ft3»-Mj£Mfl| 5 4
£?\ JP£ 1 5 wm©iiTM?n5l-*t#5 lOlC, ^6
8 lfclftSU If bttJb^a*-j|?>M (B##-tf> (flj) ^CDSE
G-R) SV-^tbTffl^Tm^lf-A^JtStfV^ J»$2AtmO^
WO 03/021706
19
PCT/JP02/08897
•~^>-vmm^n^m-mmm^nm5 2*7«bfc. 06k:
»Sifg'T*j£3n£S£-&tf# 5 l ±(ctx^ 8 l ^iSMTSli^ £tk
Ufco 06© (a) fc«±SiB|£^U 136© (b) fc ttffi|®B £ L,
7co 1 X 1 0" 4 To r r ©A rgHft«ffifri< Mm^Ptf-
A©jna«jE*j;^m««, tnfni o k v^^rsi a/c m 2 t Lit.
•o€\z. S-OiSj5«RI 5 2 ©±1:0 7 K^t«fc 5 l: 1 . 4 cm
Mm&mni&*iitz>z^>uxmm(D-?z?7 8 2 §gi»u l i 2 s -
S i S 2 -L isPO^^-^y hilTi^TRF7^^hD>^^5/
■^ScSfrVi, 2 //m©L i 2 S - S i S 2 - L i .P O 4T**#$tt*
it7^^8 26Ktt5»f*wl/fc. H7CD (a) fc|i±IHS^
U 0 7© (b) KlttlKlSHfew'Lfc. £©££, 1X10 Tor r
©Arll^&l^, 10 0 mm* y MM X# «fc rjc 1 o 0 W
§SC, @ftm#P»Jf 5 3 ©±fc, 08 ^^Tek^ fc, 1 c
c o 304§y-xi isxm^x &mn?¥-j±M%m &fr^, j?£ 1
Atm©L i Co0 2 ti^^n§iriig«H 5 4 £ d
^ 18 KlttBtiMtffiJtJI 5 3 ±fcTX£ 8 3 fcttH-rsfc^SasLfc.
08© (a) tc»±I0$f b, 08© (b) fcttffliSHfcjRLfc. £
©<fc#, 1X10 ~ 4 Tor r©Ar50 ckOTSf 5 0 %©^^^X
^am^rfflVi 7 j^Sftte) , L i 2 0»C^f^«^tf-A©
MUEEfe ct * ^tl^n 1 0 k V& J; 0 . 1A, C03O4HM
fs«^if-A©iiP3isjE*«k^«E§^n^ni 0 k v&j^tjc i a t
DTCo V-Zt&mtmMte 6 0 0 mm, gi0fc8i)0^t 7^- 1 2
©raftNfK* 6 o#f?H£L7co intgffiiisi 5 4 ^i^tsKo^
WO 03/021706
20
PCT/JP02/08897
34*6Ar ^Alfc,
Ilttl0 0mmil/fc,)i*, ^#fl5M^m ^TtiOI
o^t, IzliffiiH5 4 0J:[; > B9fc*tJ:3fc, lcm^
§^-S«^$^^Lfco 0 9fctt, SH-*ffiJg<J&RJI 5 40
±m^8 4ftRlt5«ftSlt. 09© (a) fc«±ISH*iK
U.H90 (b) ttt«ii0$Sl/ft. £0££, lX10- 4 Torr
©Arfl^^n, *^t*-A0Mmj£&=fctf«^te^-ft-£ft i 0
kV|5j;U;iA/cm 2 itfc. COJ;5fcl/T l J3 :, ^A-^S}|§^g
8-«««*Kfi5 4£^T5|fc0g;fcSftiag (t:) &£z$%-
WO 03/021706
21
PCT/JP02/08897
nmmmmm 5 4<Dxmmftrt9->k&v&¥H¥m (a e g) *m
%m-mmm<®)»m<D [003] , [ion [ 1 0 4 j ©iu#t
if ^O^fit¥*I« 0 . 2' UTtJ&ofe, -7j, Wf8, 10, 1
■ ©K*fc3fitJ<«^©aifc** (LiCoO!(il50mAh/g) §
V*T*«*«fc. 5 1M *»B©£-**fiH&K©Jil&*«£fc 0 ©
7#MS£S 1 HtkL/Co Sfc, HI 0 fc 5 a
snTv^s ^^Jiasns t>n»©"5-&. 1 ~ 6 ©$«;§■:«&
£©3§-&, #fi©M'>te, Jniim£E2 0 0 V<Dn*1fimHZtl1tZ t\Z
£*oT®fcmmmm 5 3 ©fig#±nLfcfc«>, 5 3&jg
WO 03/021706
22
PCT/JP02/08897
to o 7c z. t fc «t § t> o t #x. 5 fts .
WO 03/021706
23
PCT/JP02/08897
en
m
B
CM
CO
oa
co
LO
03
oo
CO
CO
oo
CO
LO
LO
oa
e'-
o
CD
oa
CO
OO
CO
oa
CD
•feral &°
^ ML ^
x ' — '
o
o
o
OJ
cd
CO
o
oa
CD
CD
CD
CO
CD
CD
CD
LO
en
CD
CD
o
oo
oo
CD
CD
LO
OO
CD
CD
oa
LO
OO
I
■hrtfl ^
LO
CO
O)
CD
cd
to
oa
oo
CD
oa
CD
oa
oa
LO
CO
CD
CO
T— H
CD
CO
CO
CD
LO
LO
LO
CO
oa
LO
CD '
oa
CO
CO
OO
it
•71/
Q
TO r\ J-3
a
o
o
CO
LTD
>w
<
a
o
cd
GO
lo
o
cd
CO
lo
<d
s
o
CD
oo
LO
<c
i
I
s
CD
CJ
CO
LO
v — '
<c
a
CD
O
CO
LO
L-
a
o
CD
CO
LO
Lh
<j5
a
o
CD
CO
LO
<:
a
CD
O
CO
LO
l—i
a
CD
CD
CO
LO
^ — '
1
i
1
§3
O
-h
L-t
<
o
t-i
<C
«*
O
-f-
-<
o
-4-
f-i
<c
•4
o
-+-
<c
o
L-i
-<
pa
CD
-+■
M
o
Lh
O
•+-
<<
•<«
o
-h
Lh
<
O
-h
Lh
o
-h
CD
-h
«■«
CD
-4-
<c
o
-4-
<C
1
L>
<
oa
*C
03
CD
<:
oa
CD
<C
oa
>-"
CO
a
a
CD
LO CO
a
cs
CD
LO OO
oa
CD
CD
oa
oa
CD
<
oa
>-*"
CD
CD
oa
O)
CD
*c
oa
CD
CD
oa
<c
oa
CD
a
a
CD
CD
CD CD
LO CO
oa v — '
a
CD
O
CD CD
LO OO
oa
1
IK
lirr
W
TO ^
DTK +- 1
tit
is
tit
«
18*
m
tit
Hi*
m
tii
m
«
a
I
{ton}
pr
-ii
or:
If
ijpr
r<
Vn
*
rs
i
1
e
m
i
^>
1
o
If
up*
ff
if
iHfl3
ipr
r<
a
0
ilrnit
a
Omfl
sn Pn
T— l
CXI
CO
LO
CO
00
CD
oa
CO
T— (
LO
WO 03/021706
24
PCT/JP02/08897
Hi£0iJ2
&43, HSfcS-Sf 1 6 43j;tfl 7 C43HT&, ^n€n#7^A»2 3
iillt33*5Ssc cm©gftMTA rjJX^IAl, XxmifeW7 43
5^6Ar 5 0%43j;tfO 2 5 0 %O^-&^^ ( 1 0 s c c m) £
&*&U mm%&t>Z 1 X 1 0 ~ 2 T o r r \ZMW.Vtz B
&tc. 1 8 43£tfl 9 K:4bH>Tte\ ^nftlif^!Af23
*±tf33*65scc mOiHTA r;!JX$iAL, tfXftifcSt^ 43
ck£Jv3 5*6Ar 5 0 %&&tfO* 5 0 (lOsccm), £
Mt> IS^EASlxlO-'Torrtlllfc,
[Mi]
^m^m\zn^xm^vrcm-mm^^nm 5 4©m##t^ 1 c
V m^-U%%^%^m\Z £ Kin ofc 0 HIfc#-Stl 8*itfl9©Li :
C o : OMfitS 1:1:2 fcifiV^*, SHifcH^ 1 6 43j;i;i 7 ©if-^-
«o©jt^i . immtmmtfspisxmisT^zmfoiz&z
^^#^- 1 6 43<ktf 1 7 t§g*&M^Ji,£>ft&^-?fc £ £> ,
Hifc#-5f 1 7 ©«^flBWO»^fc'b^«#^ 1 7 <Z>«£&Hft£ft*#t
WO 03/021706
25
PCT/JP02/08897
® u ^ v a -&mm \Z -D H X
MM
/I 7 —
mum
Li :Co:0Hf Jfc
(mAh/g)
Li
Co
0
16
if
40V. 2A
Ar
Ar+0*
0. 96
1. 00
2. 01
125
17
7° n' i
40V, 2A
Ar
Ar+0,
0. 98
1. 00
1. 98
125
18
'%=?
1«
40V, 2A
Ar
Ar
1. 10
1. 00
1. 70
106
19
r n' ■?
40V, 2A
Ar
Ar
1. 05
1. 00
1. 76
95
mmm 3
Li 2 S-SiS 2 -Li s P O ^xm^, £ tl5 El fttSSI 5 3 0±fc
L i C o0 2 Ti^$H5irlIffiftSI 5 4
X 0 $It ft fit ¥>S, *J:lX*HWK:#6hfcU ^^A-^^m©
I
WO 03/021706 PCT/JP02/08897
26 ,
zmfatf&znrco z.n\t, Jx\mni£<D±g-\ztbfc-DTMMx.*)V¥
S3
if #nii
X R D
m m
«E(V)
CC)
(mAh/g)
20
5
121
3. 10
12
21
10
160
1. 70
55
22
20
205
0. 60
90
23
30
228
0. 25
101
24
40
265
0. 10
124
25
50
281
0. 10
126
26
90
314
0. 10
115
27
100
319
0. 10
107
28
110
322
0. 10
98
29
200
354
0. 09
68
^^muz&^xit, m^mmnm 5 3 zmfc-tzumtLTL i 2 o
-v 2 o 5 - s ioiSffiv>, 36—mm®nm 5 4 ©^^##$^4 \z^
WO 03/021706
27
PCT/JPO2/08897
JP£2. 2iimOA-3|f>tM$tl5MIS
#JltJI 5 2 £Mt/fc 6 £©££\ 1X1 0 ~ 4 T o r rOAriJ^II
^^ffiv^ MS^t*-£©Msm&j;TOM^n^*i i okvu
Otffc, 5 2 ©±{C, L i!0-V 2 Os-S iO^
/im.O L i 2 0- V 2 Os - S i O 2T?fifj&$ ft 6 ®#«$?|fl 5 3
Ltco £<Dtt, lX10- ! Torr©ArjJXliI§i^,
y MMX£ 1 0 0 mm* tb, ^JltfcH^Sl 0 OW-tlfc..
•3«ffc, H#*#RJi 5 3 ©±fc, L i 2033 .fctfN i O^V-X t
UT.fflV»T#M*£-A**JSfcffV>, Jft$ 1 Mm(7)L i N i O2IT
#J«£tt3Sgi:*ffigf&M 5 4 £JBj£Lfc. fc£U ^uTlt IX
10" 4 TorrfflAr50 X*«ktfB6$ 5 0 % ©^-^^X^H^^ffl V>,
l i «ofc»'T5* ; ?if'-A©*nji«jE*«fct;«aEtt-en-?ni o k v&
[ff«]
4d*6t>^*«t"5K:, ^## 3 6 , 3 8fc<fctf 4 0 *^SS+fc#fl>SI
KStm&fhB K«fc3ftigfi£j&*3 5 0 ■C*je^tfc. ll#^3 0
- 3 6, 3 8 ^J;tf4OT?ttLiNiO ! 0 [003] > [10 1] £ £
[10 4] ©®3f{t-3©¥«¥«ai0 . 4 0 KTt^ofc. £
WO 03/021706
28
PCT/JP02/08897
M-if 3 7, 39*5j;7jr41~4 3 T \t f D - h* ftff ^ VfrmMT $ &
#ASttTV>*£^iiatt**»#^®rt, $1*#*3 0-3 5 0^*
Umm-xm^h^fcf)^ ^i#f3 6 ( 3 8&J;7JU 0
Mii>LT^7t, llP3I«iE 2 0 0 VC?lf«i§nfcu
tfc £oT@#«$!3|Jl 5 4©&g#±#Lfcfcs&, im^l5 4
3 7, 3 9 *J;«4 1-4 3C[)§i^ifcfiTl/TH
WO 03/021706
29
PCT/JP02/08897
bo
CO
CO
LO
r— <
cn
CO
LO
CD
T— <
CSJ
cr>
to
CD
o
en
03
CD
OO
OO
LO
OO
CD
cn
jnp
bo
CD
•o
CO
LO
CO
CO
co
CO
CO
co
CO
OS
co
CD
»— <
cn
to
cn
CD
CO
oo
OO
CD
LO
CD
CD
OO
CD
CO
m (\
m
O
CD
o
CD
CD
CD
CD
o
csi
m
LO
CD
CO
oo
CT5
LO
CO
to
1— H
CO
CO
CD
CO
CD
CD
CO
CD
LO
CO
CO
LO
LO
LO
CO
CO
LO
OO
LO
CO
CO
to
to
to
K
g J*
1$
>• ✓
✓ — \
E
o
o
CO
LO
$— <
S
o
o
CO
lo
Lh
-<
a
o
CJ>
CO
LO
<C
a
o
o
CO
LO
l-H
<
1
1
'a
o
CO
LO
Lh
a
o
o
CO
LO
L-c
a
o
CJ>
CO
LO
<c
a
o
o
CO
LO
Lh
■<
a
o
o
CO
LO
t-i
<
a
o
o
CO
LO
<
1
1
ft
LO
me
111*
E
o
-h
t-H
O
■+■
o
-h
o
-h
<
-f-
Lh
<d
o
-h
<
o
»— (
<
o
Lh
CD
o
<C
o
-f-
<<
O
-4-
(-4
<c
o
-+~
t-,
o
-+-
1
[>
>
co
CO
CSJ
Js^
CO
CO
CSS
>>"
co
CO
>
CO
CO
a
CD
) ^
( CD
lo r—
a
o
LO C—
<
Csl
>"
CD
CD
<
CSJ
>
CD
<<
>"
CD
CD
CN3
<c
CSJ
CD
<c
oa
>■"
CD
CD
csa
<c
CD
a
C3
CD
CD
I Q
CD O
LO OO
CO ^
a
CD
CD
CD O
LO OO
oq w
ft
til
m
&
m
Hi*
m
m
m
HI*
B
Kt
m
m
«
m
tpr
H
Ml
■■?»
■Off?
la 1
tf
i£MJ
tpr
r>-
v<
»rs
v<
irs
a
i
•
m
1
i
D
pr
if
Iff
tfnm)
pr
if
Iff
r>-
o
V<
>r\
0
rs
ft
Ptl
rs
A
cd
CO
i — «
CO
co
CO
CO
CO
CO
LO
CO
CO
CO
CO
OO
CO
cn
CO
o
oa
CO
1
WO 03/021706
30
PCT/JP02/08897
5
*mm>\T°\t, m 3 k^i-m^wll i (Li,/.Ti,/,) o^n-m
fiK^ns^-ii^tiii 52, l i 2. g p o s. sN o. 3 *T°mf&znz>m
#1)IRI5 3, L i Mn 2 0 4l?i^$ni)IriiS|5RI 5 4, &
Lfc. ^n^Ol§, «^ fc'-A^*£&£^fM#&£^Tiiif§-b
Li »0:fe «fctf T i 0!§y-Xt IsTm^T&Mtt H-A^*^tf lr>,
J¥£2. 5|imOLi (Lh/jTis/j) 04Ti^$tl^I-«I^i
Kl52§^^b7t 0 iCit, lX10- 4 Torr©Ar+li (g
*Jt-i : i ) fll^ffl^, Li sOicMTsit^ tr-Aoina*£E* «k
^ijisfnfn i o k v&cktfo . utb, t i o 2 \ztttz>mi L tr
L i 2. 9 P Os. s No. S6 l?«^$n5I#i)|»l 5 3§f«lfc. l! <D
1 0 0 mm<f> <h L> ffi«£t}£& 1 0 0 Wt bfc.
S#tiSI 5 3 ©±fc, L i iO*«ktfMn Oi*V-Xi:L>TJB^
T^M^lf -Ai!l*8*fr V>, J?£ 2 (t.mOL i M n 2 O 4 T?#l/$ $ tl
3fg-mgStlStJi 5 4 ^lllfc. lX10- 4 Torr©Ar50%,
S$50 X©a-&^^»B8ftftfflV>, L i 2 Ofc^-rs*^ tf-AOin
atS*<ktft»Sfnftll 0 k V43£lK0 . lAtt, MnOiC^t
T 5lf tf-AoanMJE&^tffcSES^ft-eni o kv^itf l At
WO 03/021706
31
PCT/JP02/08897
5*6t)*5J;5l:, MS^ 5 0 , 5 2 £ «fc 5 4 ^JS* MftH
*tfMftW-6IC«fc**lif«ft3ftl 3 5 0 t*jfiAfc. *&, M#f4 4
~ 5 0 > 52*S«fctX54fc*V»TttLi ; Mn % 0 2© [111] ©[Uifrfs-Sf
0. 2°RK$^;, -J, IMf5 1, 5 3feitf
5 5 - 5 7 Ttt^D- Kfcfc*l/#M*C*ft#ofc.
£>ftTV>3 i^i$n§*l#§0fi, *^#-^4 4-4 9 (D&M.
M'>bT^7c„ MHE2 0 0 v®**#jswsnfcj:
£K:«k"3T@Mfl?SS 5 4 ©ja«#±#b&"ifc«>, i#l«SI 5 4
ttfc. M#f5L 5 3 &=fcrj5 5 ~ 5 7 ©M*t*ttfcHKT l/TH
WO 03/02170<>
32
PCT/JP02/08897
in
ml>
m
?
bfl
M ^
to
CD
cd
CD
CD
cd
LTD
CD
00
00
CO
cxi
LO
CO
CO
CD
LO
cx»
CO
OO
LO
g
x *r ^
cd
CD
0
CN5
CD
CO
0
CXI
cd
to
»— 1
O
CD
CD
CO
CD
LO
»— X
CD
CD
CD*
CD
OO
00
CD
LTD
OO
CD
CD
CNJ
LO
OO
« sa -
OO
C—
CN3
CO
CO
O
CN1
CD
LO
CO
CO
CX|
co
CD
LO
CO
CO
CO
CO
CO
LO
LO
CO
l-O
LO
CD
OO
C^-
co
IS
w
K
•mj? r% iaj
g fit 5
0
CO
LTD
•<
m
CJ
0
CO
LO
x^
<s
s
CO
10
i_i
■<
O
O
CO
10
<
1
1
a
0
CO
LO
0
O
CO
LO
<c:
E
CJ
CO
LO
t-H
<
S
c_>
0
CO
LO
■<
m
0
CO
LO
S— <
<C
m
0
CO
LO
S— t
«<
I
!
« I
Ml !
O
"f-
f-t
.<
0
-h
O
-h
«<«
0
-+•
l-f
.<
«««
O
■+■
M
O
-<
O
«+-
l-i
•<
0
-H
Lh
O
-f-
J~<
-<
CD
O
-1-
Lm
*<•
0
-h
0
4-
Lh
-<
0
-+-
Lh
1
l>
»<-
-<
LO
CO
LO
<
CO
LO
<
CO
>
LO
d
CD
) ^
C CD
lo 00
m
a
^ ^X
I S
LO OO
CO
>
CD
C3
CXj
exj
CD
cxi
>■*
CD
CD
exj
•<
exj
CD
>
CD
O
cxi
CXI
>■"
CD
a
a
CD CD
LO OO
CXI x-^
m
a
CD
CD 1
I £
CD CD
LO OO
CO s — '
Ml
§3
Ife
1 K>
si
SI
m
tr
11
IK
M-
fff
r>-
V<
>rx
rx
Vs
s
•XX
1
0
r<
S
1
ipr
|f
If
if
if
rx
V<
»tx
a
*
0
rx
«IX
m
ilml)
vjj PJj
LTD
CO
t—
-^
00
cn
CD
Lf3
LTD
cxi
LT3
CO
LO
LO
LO
LO
CO
LO
LO
WO 03/021706 PCT/JP02/08897
33
]¥£ 1 5 jim(D«|«$n§i-|«# 5 1 0±fc> LnN^J;
l i 3-oC o .NTM^nsfg-MMfii 5 2 zmj&Ltz. zot
£&3©^4tfcff2:b^ofc 0 1 X 1 0" 4 T o r r ON^'X
^niOkV^i^O. 2 5A£L, C o fc^T £ ft'? tf-£
jEE^^t^m^^^-n^ni o k v*3=t^i At htco iffiiiffl
oittc^^TB, m^Mmj£&4ov> m^nvaz 2 a, #x#a
f 2 3^5C5^^iIS5 s c cmtl&t
O^C, S-«ffigftHI54(i!)±ICL iiS-S 1 Si-L l l PO <
2Mm©LiiS-Si Si-Li »P O 4-e*S#£ ft3 ®#MSJ1 5 3
£^$Lfc„ IlOtf, lX10- ! Torr©Ar^lll^ffl^>
MMX& 1 0 0 mmi KJ^&m*!* 1 0 OWtlfc.
tr-r A^stJSfttf v>, mis 4 jLim©v 20 6T«^^n§m-ms^
©Ml 5 4 ^flSbfc. iKDfg-mSTStlKS 5 4 OJ^dtKl^VsTttx
1 c mntOJE^Hifim^tz7,T>^7,n^^^ (BZ 2 0 Mm) £0
5 3 0±C«t$tTISlb, c-V 2 Oj$lcmH0^
MfcMLfco d©£€N 1 x 1 0 ~ 4 T o r r (DA r & J; ?>* O 2 <D *I
#X (1 : 1) *H«*JflV>, A^-^^AK^-rsti^tf-AOjlPiim
WO 03/021706
34
PCT/JP02/08897
SI 5 4®±fc, C u SV-X ibTJBV>T**E-AlK*»fcfTV>,
J¥£ 3 /im®Cutli^tl5|r«i#5 5 £J&J&b£:.
1 cmAOjE*»»n»Stt5Xf (f$2 0|im)
sa#««pRi 5 3 ©±K:$3»$-a-Tg*iiu m=.mmm^mm 54©
§lcm^0»ttHffi^fc. £©RK IX 1 0 ~ 4 T o r r © A r ^
*HH^£fflV>, tf-A©iDMBE:fc«ktf*i«£*-n* r tt 1 0 k V
tefrofc. ^i&S6CSlfc. S6fc^T«fc5fc^»##5 9,6 1
6 3 £«*c#^M*HS^f|-6 fc«fc 3 5 ot§
SAfeo $&, 3lJ^#-^5 8-64, 6 6*J:tf68t*^TIt
V 2 0 6 © [200] , [221] [240] & 2 © telSr flt^CD ¥
-71 T&7n- Ffcm^bfrSSJTfSfcjfcofc.
ft6nfc'jf9A=*««ift, mmum2ov, o. 2ci/-
h (i?i!SOli§IS5^f|T?SiTf5i!Hi) t3. 2V^T'^1
u 2ci/-h (liciifis i/2B#^-e^«-e#§milEffi) T?
1. 5VJt|![l5tfe. 5t^^JV@0^rigffi*lIiSfcDO
WO 03/021706
35
PCT/JP02/08897
6 9-7 1 t«^iHiZifEtI^ITbT^5, ^n«c - V2O5-?
WO 03/021706
36
PCT/JP02/08897
mV
m
m
'Si
»^
CO
co
cn
to
CO
CO
CO
o
LO
CD
CO
CO
CO
CO
CO
CD
OO
^
CD
CO
^
LO
OO
^
CO
CO
r~
Ti-
1— t
CD
OO
CO
CO
CD
^
Ml
S?
« f ^
CD
CO
o
CO
cd
O
CD
CO
CD
CD
cd
CD
CD
CD
CO
CTJ
O
CD
CD
en
1—4
CD
O
CD
LO
OO
LO
CD
CO
OO
3» ^ Q
W 5S -
CO
CO
CO
LO
co
an
LO
CO
CD
CO
CD
CO
LO
CO
CO
C—
LO
CO
CO
CO
CO
CO
CO
CD
LO
cn
LO
CO
OO
LO
CO
c—
CO
1— «
it
K
as
m
K
•n^ r> «^_3
mm S
/— >s
a
o
o
CO
LO
s», '
5
o
cd
CO
LO
v— '
*-i
<c
o
o
CO
LO
»—
a
o
o
CO
LO
t-i
I
1
a
o
o
CO
LO
a
o
o
CO
LO
%-i
-<
a
o
o
CO
LO
t-H
a
o
CD
CO
LO
Lh
■<
a
o
CD
CO
LO
"W
E
o
o
CO
LO
■« — '
<
1
i
o
-+-
Lh
o
-h
Lh
o
-+-
<
o
<:
o
-4-
<C
CO
o
-f-
Lh
o
-4-
o
-h
-<
o
4-
o
-4-
o
-h
Lh
O
1-4
<
CD
-t-
L-i
o
■+■
Lh
i
CO
>-""
CD
CXI
>»*
CD
CO
>-*
CD
<
CO
CD
"^
a
a
CD
* s
LO OO
a
CD
I %
LO OO
1—1 v —
-<
CO
CD
CD
CO
-<
CO
CD
<
CO
>-
CD
CD
CO
<
CO
CD
<
CO
CD
CD
CO
CO
>
CD
a
os
CD
CD
I £
CD CD
LO OO
CO s —"
a
CD
CD
CD CD
LO OO
CO s - / '
m
w
ffl
Ik
&
4-lVt
TO
J!)K
tfnyLt
m
53
fR
^
m
w
m
pr
il
TO
m
ff
tpr
If
ipr
r<
o
rx
r>-
r<
>fx
0
rx
1
0
r<
t
e
r-<
9)
lb
HP
If
Iff
tf
Ml
(pr
If
Ml
iptr
r>-
r<
e
rx
v<
o
0
*
v
sjj Pit
9
oj Pn
oo
LO
era
LO
CD
CO
CO
CO
CO
CO
co
CO
LO
CO
CO
CO
CO
OO
CO
CD
CO
CD
C~
WO 03/021706
37
PCT/JP02/08897
mmm7
Li 2 s-sis 2 -Li 3 p o <T*mf$z n&mfcnmnM 5 3 1,
l h-,co a NT:ffij$.isnz>m~mm%y>}nm 54t, c uti^^n
Sf, W£ 1 5 /im0|«T«^tl5l-il* 5 1 ©±{C,
$^A£V-X £ UTflH>Tl|^l£-AM£fT^, J?$4jtzm0c-
V 2 0 5 T^j&£nSfii--M?£t)Sf® 5 2 £^J&Lfco IX
10- 4 TorrOA r £ £tfO 2 ©SI£#X^M 1 : 1 )
vi, n-ywA\zi$ t:-AcoiPii€JEfecfctx«^?:, ^n^n
rokv^i^iAti, sfeMMfflaiP in 2 1 m ; ?*RBS*bfca*&
s^^tfofco ^Mfflm^$i2 1 ftTjraiiE& 4 o v,
S^mgft^ 2 A, ^/XiAf 2 3*6CAr tfltfi£ 5 s c cmtlfc.
9ft, J|-ttlffi«ai5 2©±tLi 2 S-SiS 2 -Li 3 P04
2/im©L i 2 S-S i Si-Li s P O 4T#lJ&$ ft 5 0#tt$ftJI 5 3
£tML7Co lX10" ! Tor rOAr^Xlll^ffl^,
$^{I V 0#m#?StJ! 5 3 Li.NfiitfCoSV-XtLT
JB ViT^JSK'f tf — A3R»J**ffV^ #3 1. 4(im0Lis-.CO.N
1 cm^OIE^f ?L*i|i^fc^f>kXU77^ (J¥$2 0/zm) £@
i^iill 5 3 <7>±£®*£iiTi£gU L h-.Co .NTilSSns
WO 03/021706
38
PCT/JP02/08897
£ , 1 X 1 0- 4 To r r0N,XfX»H«*«n, L i aN tc# <r -SH^
^-A®ina*JBE^ < k^«ft^ n ^ tll o k Vfe^OtO. 25AtU
ttmwmmmms 3©ifcftsttiiu M-mMMg 5 4 ©
±tec.u*c*«an*»-*«#5 5 safcfcttjBT?, «z*t# 5 5
Slcm^MfcWbfe, CCDif, lxiO- ( Torr©Ar
l i.-.co.N© [ioo], [ioi]^w[no] &£©ia*r
WO¥l*i^0. 2«HTT^&. -J! »H7 9, 81*
WO 03/021706
39
PCT/JP02/08897
nx^zmmm'^vft, ^^#^7 2-77 ^&iwi-T&$y-e&^£:
*», iW7 8, 8 0&£tf 8 2Ti^fi^M/>bTV>7c. CO^fi
®»'>tt, MHEE 2 0 0 V©«^dtflBjW*n&2:i:fcJ:5Tia#««P
8 3-8 5 fflfC t^t&^ofc. :nii,
L i 3- a C o .NTii^nSIriMfl 5 4 ©»lltt^3S^T?
* o fc C i fcjg H 1" * t # A & tlfc .
WO 03/021706
40
PCT/JP02/08897
mid
m
M ^
CD
LO
to
CD
CO
CO
LO
O-
CO
CO
LO
CO
co
LO
CO
LO
CO
o
CO
LO
CD
^
OO
CO
LO
LO
LO
CD
LO
CO
CO
03
•tad 130
f— <
CD
CO
00
CD
LO
CD
CO
CD
LO
i— 1
CD
CD
CD
CO
CD
CD
CD
en
CO
CD
LO
OO
LO
CD
oa
00
M ^
oo
CO
00
CO
OO
F~
LO
OO
OO
00
LO
CO
00
O
CO
OO
LO
CO
CD
CD
CTi
LO
CO
CD
LO
CO
LO
CO
CD
CD
CO
*"t —
in
m
IS
•CJT? rS w
H
o
o
CO
to
is
S
cd
o
OO
to
is
H
o
cd
CO
LO
S
a
o
CD
CO
LO
V— '
«■>»
ss
1
a
o
CD
CO
LO
ra
!S
s
o
o
CO
LO
c»
iS
a
o
CD
CO
LO
CM
a
CD
O
CO
LO
CD
CD
CO
LO
•w
CM
is
a
CD
O
CO
LO
V '
is
1
1
ffi
:s
is
iS
is
IS
is
iS
iS
is
is
is
is
1
oo
CD
OO
CD
*c
00
CD
OO
CD
a
a
CD
I s
LO
s
S3
CD
? 5
LO C—
, | '"w'
<c
OO
CD
O
OO
-<
OO
CD
CN3
CD
CD
CO
CD
OO
0
0
00
00
0
a
c;
CD
CD
CD CD
LO OO
OO '
a
CD
CD
CD CD
LO OO
00 v — '
m
E
m
Ml
TTv
58
t&
is
♦ft
t l\l
W-'
fefc
top
ipr
ii
Ml
s§
If
If
flpf
v<
o
r>-
a
i
i
o
r<
•EH
^ 5
m
*:
1
e
<
if
1 tiuT
If
If
Iff
If
Ml
JljiHr
r>-
Vc
»r>
rs
V<
0
ilmtl
ttfnil
Pn
OO
t—
CO
o-
LO
O-
CO
o-
OO
c—
o-
CD
CO
00
00
00
CO
00
00
LO
OO
WO 03/021706
41
PCT/JP02/08897
^BM 8
-i«#6i, l i c o ozT-mi&znzwi-mmmVdMm e 2 , aflsu
6 7, L lC o OtTKIdoSn* H-tilSWll 6 8 , *5 «k C u T «
^j^s^jf $-&Tij^$-&feo Sinn ?smii^fc«i?&L, mmm\z
*f, |Sl>mOLiC o 0iTrfl|j$£n5&-««?£«lSJf 6 2
ft&£pmk:&££1£5ll£fc£oTfTofc. H-MMKJg 6 2 ©
WO 03/021706
42
PCT/JP02/08897
£ 2 0 urn) £C umT*mi&ZtlZ>%-MmfcQ 1 ©±fc^£i±TB
LiC o 0 2 T^^$n^^-llS^tl®Ji 6 2 * 1 c m^©JSg^^
1X10 " 4 Tor rCAr50 %3$&Z$M% 5 0 %<D?I-£
te^-n-^n lokv&itfo. 02Aib> ^ico c^-r^mTti-
AroMsffi&^tfttM^n^ft 1 o k v&&zto . 2Atife, v
-X^£>M£T<Z>Sg|iHj;2 0 OmmiU §3M©7c & <D «> * s>
^JXiAf 2 3*6®Ar 5 0 J^'MSf 5 0 % $K
»fct 5 0 s c cmilfc. H!fc#-5f 9 6 fc&V>T&, X*)U*r-
•o€\Z, L iiP04S^-y»;htbTffi^RF7nhP>X^y
^L^S^m^lHii 6 3 SjgjEfcbfc. ^ffli^lX10- 2 TorrOAr
#^i?B^;£J3V>T, ^-y»;hHXS10 0ram*, ilMSfiiAS:
10 0W, dt«|l$W§3 2BKfcL&. *&, iE^7^?L^M^7cXx>
l/^avx^ (ji§20/im) ^m-mmm<^mm q 2 mm
#6 1 <D±\zi>imfcmK)%M2ii:-T:mmT%z.t\z&r), licoo^
H#m^»S 6 3 CD±(C, Jg#tUnSft&*8c*fflV>T/*3 0 . 5 Aim©
l i -cffif&ztizwi-mmmvonm q 4 z.<dwl % m^mn
^tt§Xf>l/XS7X^ (J¥£ 2 0 u m) fc, a<bu >«U ^ A
titj&snsii&m^ftJi 6 3&cfctfc u-?«ii$n5Mi*6 1
WO 03/021706
43
PCT/JP02/08897
164$, fg-ttMi£^Jt® 6 2 ©±£BV>2fer3 0M#R» 6 3 ©±
O^fc, 3fcttJU*ffi&fcfc5J*3 0 . 5/ira0^INiTli$ns
6 5 £JB/£U J?£0. 5 /i mO^I L i T$fj&£ *l 5 » =
«S*£4fc5?R 6 6, *<fctfJP£ 2 /tmOgfbU >iUff)Ati^$n
J? « 6 7 JI$2^m0L i C o0 2 T?ifiK$n
smmmmmwunm 6 8 sjBjfcbfc.
urattStstifiJi 6 8 sjg/fcT a »©&#&*, 3S-mjs*kb 6 2
T&D, I2I 4 K*T£3 E-©«ffi&W-f 6 1 til
6 5 *«fctf&H*ffi$&<l&H« 6 6 £0&tt*«fcV>«fc 3 CT3&S#* o
fc. &:/ni:*&#:z?©&IIJI$©£«©*?ftBJ£ffl£&&8 fc^cUfc.
S*«Elt> T4. 2VS , Cl5«l/..2Cl/-h (ttfl&©3ffi&*& 1 /
2B#WT > ^€"e$smsstfi) t?3. o v^-e^mbfco 5*M9)VU<d
$8 K:ft|glZ9«t£j5<ftKff 6 8^J«©M©ftit?£iJii?&g> *«kZX
izgm^ffiti»i6 8^^^©«Kai»a***2 o ot:^T©isaT«,
*«fctfg*©teT**B«>&*i;fc. 3 7 5 tTtt, Jqa&fcjSBT*
WO 03/021706
44
PCT/JP02/08897
1 ~ 8 5 fce^Ttt, 2 0 0 VOjDJttBJET^fiCOiST^ig
ft6tl&OfcS#b, ^lt#^8 6^9 4IC*^ttt, 3 0 0 V©ip5i^
ftUSMJE© 3 0 0 Vlt L i C o02©SS 5 . 06g/cm\
*miCoO.O [ 0 0 3 ] S^faflte^-JtSU (1)
5* (2) IC^AUTA6n5t (E 1 = 3 1 0 e V) K jfi Wl <h b .
SlK^i: 0 feT^^{;#ftLfc@^Si 6 7 tea»ai«U S
WO 03/021706
45
PCT/JP02/08897
%8
fg-m«MJi 6 2
(V)
mmmm
(A)
CC)
XRD
(deg)
§i
(nAh/g)
86
10
7
153
—
58
87
40
10
170
0. 25
105
88
70
20
194
0. 20
112
89
100
20
212
0. 18
120
90
130
20
235
0. 16
122
91
160
20
269
0. 16
121
92
200
20
301
0. 12
123
93
250
20
335
0. 10
121
94
300
20
358
0. 10
121
95
350
20
375
0. 09
89
96
140
23
bf;. !3l;itlil^U Cu-(?M$n5i-ii*5l, Li
•ei^Stl^I-li^ftll 52, c-Li 5 P0 4 -L i,S iO.T
WO 03/021706 PCT/JP02/08897
46
1 5 f/raOC u$ST?«fig3n3lli-**#5 1 0±fc, L i Sy
^Jtl^I-ilgtill 5 2 fcJgfiSLfc. i©^-|iffiftil 5 2
O-hfc, Li a P0 4l L i i ^V-XtlTffl^THMf t?
-A«i**ffvi, l i a po<-L i ,s i o^Mfcztizmihnoimfc
mmmm 5 3 zmatLtt. ecu, Mifif-Ac^tLTit
lPiS«ffil O.kV, lOmA(Li), 120mA (Si) ^^^80
mA (L i 3 PO<) %m^s fOttC^i^^A r *3J;tfR*©g-&
$7, m&ft 5 0:5 0 ) t Lfc„
©** 1 3 ft«»3f, lOOtt^l/OO, ^9
50 : 50) Ctt550sccmHfc.
^9 fctt, mwmmwm 5 3 ^sg^-g^©^^^
9 7 - 9 9 Tttcr</jNSatr-^S«|»:fc?SS*r'5Ci*«*C , #
SfrK ff£ 2 nm<D c - V 2 0 6 T«^$tlS^-«^StiKl 5 .4 £'
^ t ^ S2A > ^^iAf 2 3*6© A r* J; (5 0
:50) Oll^5sccmiLfc. V -J* 6 0 0 mm
WO 03/021706
47
PCT/JP02/08897
ft5Xr>^S77i' (J?£ 2 0 Mm) £ BMill 5 3 ®± fc
$**1*T11*, Cu?ijjgh5»rlt#5 54,
Jf 5 4©±fcMfcofctt«Tl cm^OMCMLfc, £ © £ £ ®
Hffl^Uil X I 0 ~ 4 T o r r OA r> flgjt*^ tf- A ©Jd»«JE
tt^-n-^n 1 0 kVfeiDtlAilfc.
si**£ftti 7 oti r>^m^\z^mmmm^ntc 0 i&nmzM
-«ffii£*Sfg 5 2 L i J&*&V>gR#£&5gB#
®I^#I1!B#1JIS1 5 3 CWMLT^Sui^Btlfco
0{*»$SIJf 5 3 SMtSifcXfiOflflE^bfcjifcl:
cfc^T, L i ti^$tl^I-«|g|jf| 5 2 ^-^WfcJSMLT*
$5*&Lfc&»#*| 1 0 0©*^flBjtS*©Jni$«JEE 2 5 0 V}1,
^ ( 5 ) ^^73*^ ( 6 ) \zmwmmnm 5 3 ©&^ 2. 5 g/ c
tf&T£&4 AmblfenSffl (E 3 = 2 2 0 V) cfcOfeffi^M
WO 03/021706
48
PCT/JP02/08897
^9
m&nmwm 5 3
(V)
mmnm
(A)
CC)
XRDjf
(mAh/g)
97
100
20
209
58
98
150
20
215
% D
89
99
200
20
240
86
100
250
20
278
101
140
15
1 0
**#51, LiT?M$tl5$-liffiliiSl5 2, C-L13PO4
-L i <S i 0 4l?ti^$n§@#:«^M^ 5 3 , c - v 2 o 5 T«^$n
SffcSJK:, ffS 1 5/tm©Cui«$n§I-il#:5 1 ©±
WO 03/021706 PCT/JP02/08897
49
\Zs l i &v-x£ Lxm^xmmmmm^m^n^s mzo. sum
■<dl i xm^^n^^-mmmmnm 5 2 zmi&Ltc, oti;, z<d±
fc", LisPOA, L i fccktfS i $V-Xt iTl^TEiStf If- A
^»SfrVi, IfciiHOL i 3 P O 4 — L i 4 S i O 4T*ti/& $ ftS S#m»
ff«5 3£ML7Co tf- A -t LTit *P3S
miE 10kV, 10mA (Li) , 120mA (Si) & «fctf 8 OmA
£-J£ 5 0:5 0) tlfc,
atffi*^® 2 1 (DmTmmnfc* 1 o o v, sf«s§20A,
AW 2 3*>5®A r fc£tfBI*©iB&#X (fi^Jt 5 0:5 0 ) ©^S
§5 0 s c cmiL/fe.
5 3©±(C, LiUi^Co§V-Xi LXm^X-U
bf-A&J|ti**fTV>, J¥£ 2 jim©L i C oO^W^n^grl
@^#JRS 5 4 &JBl*l/fc. &H&« 1X1 0 " 4 T o r r ©A r 50%,
iS5 0 K©ig£#X.(#*ftl&tf 7 SEW L i fcfttZ
£-A©jn»«ffifc«kwtifttt-*n-en 1 o kv&£tf o. ut
L, C o ,0*lc^t ^>«^ Vf-A©Jinai«JE*«fc^«8i8tt-ttl J E f n 1 0
kV^itfiAtbfc. ^-ilSAK15 4^f^t§^lc,
gE*IW«f 1 3 £f£lj$-&3 iltKcfc-pT, S&S®2S«
SlOOtfCft^t, * 1 0 t«t*ffft)B^&. £fc> #X^A«2
3!i^OAr^j;«iOS^^X (?1&J£5 0 : 5 0 ) ©«f*«5 0
sccmilfc, fcfc, Hitf 1 9 6(:^^Ttt> x * - JIB S* &
frfr&frofc. V — X i»«©m§l« 2 0 0 mm, y
WO 03/021706
50
PCT/JP02/08897
i-iSSill 5 4 <Dl&f&Pp <D&tiL&m<DMMm&ffi.Bi&& lot
ynbtco -ki&<D£5\zLTMf&Lf£l c m£©£§7f $© Hz: MS tilt
$ 3 <im©CutM$n5^rit^5 5MZ%J$,L, 0 3CSti
jfift^r-r^u^^A-^mjftsf^wufc. ^Mt^itit i cm
^©lE^Tf JlSttSXf^l'XSYX^ (JS£2 0#m)
« 5 4©±lc^gftofcttlll:l cmMvmmmzMj&Lft. E'Ofc*,
1X1 0" 4 Tor r ©A r ^f^#H$tftfflVi, ilfif If- A ©inSS*
Hss.ktfuaitt-eft^n iok v*5<ktf i Atu,
«■ 6 ti m » © ^ & m # it * m jfi © * » eg t a! ^ ft 13 m \z m c x w m
U ,1@Jil£^ 1 0 iZ^VfCo ZtUz&tHf, HfJ#^ 102-106©
(3) (4) laoTfi^nsl (E2=15000eV)
fto
WO 03/021706
51
PCT/JP02/08897
mi 0
%=.mm%mwm 5 4
•51* SZ. -hn nr
(V)
art A_l /sis, ?,-f?
MmmM
(A)
-H- -l«e ',a t+rr
oc)
XRDfe -i-
(mAh/g)
102
200
20
263
123
103
250
20
302
126
104
300
20
322
D
124
105
350
20
351
$0
122
106
100
ft I,
5
#Jfc tt^Ji ffl § ZL £ j&tTJ £ §
. ±iBHm^Jfc^ViT««S«tlK<i: LTL i CoOi, L i N i O2,
L iMniO ( , L i »-,Co.N, V 2 0 5 ^fe«L i (L i , /3 T i 5/3 )
WO 03/021706
52
PCT/JP02/08897
z ziz^wmmntbTU, amu ^g&u^A, l i z s - s i s 2
-L isP04, Sifettl. 7Li.O-ViOi-S iOi§ffl^&*t, *
tttt, L i fcitttEjfcbfcuaSMfr-canfcrJ: < , «AHCu, Ni
WO 03/021706
53
PCT/JP02/08897
t l o i h
\zm%sTz>ct\z±io, ttmrn-nmrnrnxm* mmm~nm^mmm
£ fc it if IB 0#mfl?StJi £^J&1- * lili & AH-r 3 H £ <h T
3. mmmT-^rcitmm^.^mmmi'. <i
ttlHfciEtBtt©*^**^©*!*!;^. •
5. iWf9BSlllXgK::feV>T7TSJ*2n*l&ft©Jl©»£&, ^-©m^fc
6. wiB»fi©mft* s , WEfiiiexsK:*nT7^j5e$nss^^©s©
WI3*«# 6CD#i*iSt« C £ £&Sfci:T3Iif$©$&Hlf! 1 JffBl!
©H5Ub^m^©MSi#&.
7 . MiB«ffltigte*viT^j«$n*s*«i^*rsfl3^«»5&«K'fk'»*fc
WO 03/021706
54
PCT/JP02/08897
WO 03/021706 PCT/JP02/08897
1/9
03/021706
PCT/JP02/08897
F I G. 5
7 9 78
WO 03/021706
PCT/JP02/08897
4/9
F I G. 8
(a)
(b)
F I G. 9
(a)
(b)
1
V/////// //////
■53
•61
WO 03/021706
5/9
PCT/JP02/08897
WO 03/021706
PCT/JP02/08897
LL
WO 03/021706
7/9
PCT/JP02/08897
CD
- LD
(a) 3 m
6
WO 03/021706
8/9
PCT/JP02/08897
WO 03/021706
9/9
PCT/JP02/08897
INTERNATIONAL SEARCH REPORT
International application No.
PPT /.TPO? /0RRQ7
A CLASSIFICATION OF SUBJECT MATTER
Int. CI 7 H01M10/40, C23C14/04, H01B1/06
According to International Patent Classification (PC) or to both national classification and IPC
B. FIELDS SEARCHED
Minimum documentation searched (classification system followed by classification symbols)
Int. CI 7 H01M10/40, C23C14/04, H01B1/06
Documentation searched other than minimum documentation to the extent that such documents are included in the fields searched
Jitsuyo Shinan Kbho 1926-1996 Toroku Jitsuyo Shinan Koho 1994-2002
Kokai Jitsuyo Shinan Koho 1971-2002 Jitsuyo Shinan Toroku Koho 1996-2002
Electronic data base consulted during the international search (name of data base and, where practicable, search terms used)
C. DOCUMENTS CONSIDERED TO BE RELEVANT
Category* Citation of document, with indication, where appropriate, of the relevant passages Relevant to claim No.
Y JP 10-284130 A (NEC Corp.), " " " T^B
23 October, 1998 (23.10.98),
Claims 1, 3; Par. Nos. [0023] to [0026]
(Family: none)
Y US 6066417 A (Samsung Display Devices Co., Ltd.), 1-8
23 May, 2000 (23.05.00),
Column 1
& JP 11-73993 A
Par. No. [0002]
Y JP 8-45338 A (Mitsubishi Heavy Industries, Ltd.), 1-8
16 February, 1996 (16.02.96),
Claim 1; Par. Nos. [0001], [0005], [0008]
(Family: none)
"x"l Further documents are listed in the continuation of Box C. Q See patent family annex.
Special categories of cited documents:
'A" document defining the general state of the art which is not
considered to be of particular relevance
"E" earlier document but published on or after the international filing
date
L" document which may throw doubts on priority claim(s) or which is
cited to establish the publication date of another citation or other
special reason (as specified)
'O* document referring to an oral disclosure, use, exhibition or other
means
P" document published prior to the international filing date but later'
than the priority date claimed
T* later document published after the international filing date or
priority date and not in conflict with the application but cited to
understand the principle or theory underlying the invention
"X" document of particular relevance; the claimed invention cannot be
considered novel or cannot be considered to involve an inventive
step when the document is taken alone
U Y" document of particular relevance; the claimed invention cannot be
considered to involve an inventive step when the document is
combined with one or more other such documents, such
combination being obvious to a person skilled in the art
document member of the same patent family
Date of the actual completion of the international search
30 October, 2002 (30.10.02)
Date of mailing of the international search report
12 November, 2002 (12.11.02)
Name and mailing address of the ISA/
Japanese Patent Office
Facsimile No.
Authorized officer
Telephone No.
Form PCT/ISA/210 (second sheet) (July 1998)
INTERNATIONAL SEARCH REPORT
International application No.
PCT/JP02/08897
C (Continuation). DOCUMENTS CONSIDERED TO BE RELEVANT
Category*
Citation of document, with indication, where appropriate, of the relevant passages
Relevant to claim No.
US 4474686 A (Hitachi, Ltd.),
02 October, 1984 (02.10.84),
Claim 1; column 1, lines 6 to 11
& EP 104936 Al & JP -59-60814 A
Claim 1; page 1, column 2
1-8
Form PCT/ISA/210 (continuation of second sheet) (July 1998)
mmmm^ pct/jpo2/os897
int. C I H01M 10/4 0, C 2 3C . 1 4/0 4, HO 1 B 1/06
«*f?ofc**Bam (limi n po > :
Int. C 1 7 H01M 10/40.C23C 14/04, H01B 1/06
B#S§&8*r5g2fcS 19 2 6-1996$
H^H&BS^ff^^ 1 971-2002^
H*B2SHffiff^*il 1 994-2002$
B*H*fflS?f^»»^ 1996-2002$
c. ^Si-<
Y
Y
Y
JP 10-284130 A (B#«»HsS£*fc) ,1998.10.23,
3, [0023l~[0026], (7r5y-ft'L)'
US 6066417 A (Samsung Display Devices Co. , Ltd. ), 2000. 05 23,
f&lffll & JP 11-73993 A, [ 0 0 0 2 ]
JP 8-45338 A (ZUlftS^t) ,1996.02.16,
1, [0001], [00051, [0008],
1~8
1~8
1~8
mm.
HIMtt*r*TLfc0
3 0. 10. 0 2
BREIM«o«SP 12.1] 02
8*m¥fVf}f (I SA/J P)
SSi^ 100-8915
03-3581-1101
4X 3 13 2
3 4 3 4
aSPCT/ISA/2 10 (02^-^) (1 9 9 8^7^)
BB§StbK§^ PCT/JP 0 2/0 8 8 9 7
Y
US 4474686 A(Hitachi, Ltd. ), 1984. 10. 02,
M&Kl, ^11im6=fT~^l l=fT & EP 104936 Al &
JP 59-60814 A, fflttlt&OKm 1 , # 1 K» 2 «
1~8
i^PCT/ISA/2 10 (SSZ^—WOtt) (1 9 9 8¥7^)
THIS PAGE BLANK (uscto)